Kinetic Theory of Ideal Gases

German scientists R.Classius and J.C. Maxwell had propounded the kinetic theory of gases. According to this model, every gas is made up of very fine particles called molecules. All the molecules of a gas are similar in all properties. We know that $ 1 cm^{3}$ of water is heated at $100^{\circ}C$ temperature, producing $1$ atmosphere pressure $1671 cm$ of water vapour. From this, it is known that the volume actually occupied by the molecules in $1671 cm^{3}$ of water vapour is only $1 cm^{3}$, and the remaining $1670 cm^{3}$ of volume is empty. In other words, in the gaseous state of matter, there is a lot of free space between the molecules. This fact is true for all gases. The molecules of gases are always moving randomly in all possible directions. During motion, these molecules collide with each other and with the walls of the vessel in which the gas is kept. After each collision, both the direction and speed of motion of these molecules keep changing.

All collisions between molecules and molecules or between molecules and the walls are elastic. This implies that total kinetic energy and momentum are conserved.

Assumptions of Kinetic Theory of Gases

There are the following assumptions of the kinetic theory of gases.

1. The molecules of a gas are very small, rigid, spherical and completely elastic. The volume of the molecules is the volume in which the gas is present, is negligible compared to the volume of the gas.

2. Although the molecules of a gas can move with every possible velocity in every direction, but the number of molecules per unit volume or molecular density remains the same.

3. There is no force of attraction or repulsion between the molecules, as a result of which they do not have potential energy; their entire energy is kinetic energy.

4. When the molecules of a gas come very close to each other, there is a repulsive force between them, due to which their speed and direction of motion change. This phenomenon is called a 'collision' between two molecules. Between two consecutive collisions, the molecules move in a straight line with a constant speed. The distance travelled by the molecule between two consecutive collisions is called the free path and its average is called the mean free path.

5. The mutual collision between the molecules and the collision between the molecule and the wall is perfectly elastic, that is, the kinetic energy of the molecules is conserved.

6 The time of collision between the molecules is negligible compared to the distance travelled freely by the molecule.

7. Since the amount of molecules is negligible and the velocity is high, therefore there is no effect of gravity on the motion of the molecules.

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Newton's Corpuscular Model

Newton's Corpuscular Theory

In the year 1675, Newton proposed the corpuscular theory of light to explain the existing phenomenon of light. There are the following assumptions of this theory:

1. The light consists of very small, lightweight, and invisible particles. These particles are known as corpuscles.

2. These corpuscles move with the velocity of light in a homogeneous medium in all possible directions in a straight line and they carry kinetic energy with them.

3. When these corpuscles fall on the retina of the eye, they produce the sensation of vision.

4. The size of corpuscles of different colors is different (ie, the color of light depends on the size of the corpuscle).

(A) Success of Carpuscles Theory

Based on this theory, the following facts related to light were explained successfully:

1. The light has energy: Since corpuscles have kinetic energy. Therefore, the energy of the light beam is due to the kinetic energy of the corpuscles.

2. Motion of light along a straight line: Since velocity of the corpuscle is very high, the effect of external forces on it is negligible. Therefore, it moves in a straight line.

3. Motion of light in vacuum: Corpuscles can move through vacuum.

4. Reflection of light: To explain the reflection of light, Newton assumed that when a corpuscle reaches close to a reflecting surface, then the surface repels it with a force whose direction is perpendicular to the surface and whose magnitude decreases sharply as the distance of corpuscles increases from the surface.

In Figure, let $PO$ be a reflecting surface and $P'Q'$ be an imaginary surface just above it at negligible height. When a light corpuscle moves towards the surface, then it moves along a straight line from $A$ to $B$ (since the force is zero). As it reaches the point $B$ of surface $PQ$, a repulsive force starts acting perpendicular to the surface (upward in the figure). Let $i$ is an angle of incidence at point $B$, then the velocity of the corpuscles at point $B$ has two components- component parallel to surface $V_{||} =v \: sin \: i$ and component perpendicular to surface $V_{|} = v \: cos \: i$. After crossing point $B$, the parallel component remains same but the perpendicular component decreases. At point $C$ of surface $PQ$, the perpendicular component becomes zero. After this direction of the perpendicular component changes and the corpuscles move along path CD. Beyond D again it moves along a straight line as the force becomes ineffective. If $r$ is the angle of reflection at point $D$, then the parallel component of velocity at $D$ will be $v\: sin\: r$. Since the parallel component remains constant. Therefore, comparing them at points $B$ and $D$.

$v \: sin \: i=v \: sin\: r$

$sin \: i= sin\: r$

$i=r$

i.e., the above equation shows that the incident angle and the reflected angle are equal. In the figure above, incident ray, reflected ray and normal all three are in the plane of paper. Therefore laws of reflection are verified.

5. Refraction of light: To explain the refraction of light, Newton considered two different situations :

a.) When the light goes from a denser medium to a rare medium: In this condition when the corpuscle reaches near the surface, the surface exerts a normal repulsive force on it. As a result, the perpendicular component of velocity of the corpuscles decreases however it does not reduce to zero as in the case of refraction. Therefore, enters the second medium with a reduced perpendicular component and same constant value of the parallel component i.e., moves along a straight line bending away from normal.

If $i$ and $r$ are the angle of incidence and angle of refraction and $v_{1}$ and $v_{2}$ are the velocity of corpuscle in medium first and second medium. If the parallel component is constant,

$v_{1} \: sin \: i =v_{2} \: sin\: r$

$\frac{sin \: i}{sinr} =\frac{v_{2}}{v_{1}}$

From Figure

$i \lt r$

Therefore

$sin \: i \lt sin\: r$

$v_{2} \lt v_{1}$

Therefore, from the corpuscular theory, velocity light in a denser medium ($v_{1}$) is greater than the velocity light in a rare medium ($v_{2}$).

b.) When the light goes from a rare medium to a denser medium: In this condition when the corpuscle reaches near to the surface, the surface attracts it normally. As a result, the normal component of its velocity increases. Therefore, the corpuscular enters the second medium with an increased normal component and the same parallel component of velocity and moves along a straight line bending towards the normal. 

$v_{1} \: sin \: i =v_{2} \: sin\: r$

$\frac{sin \: i}{sinr} =\frac{v_{2}}{v_{1}}$

From Figure

$i \gt r$

Therefore

$ sin \: i \gt sin\: r$

$v_{2} \gt v_{1}$

Therefore, velocity light in a denser medium ($v_{1}$) is greater than the velocity light in a rare medium ($v_{2}$).

B) Failure of the Corpuscles Theory

The following are the main reasons for the failure of this theory:

1. Interference, diffraction, polarisation of light, and the photoelectric effect, etc. can not be explained using this principle. For example, in interference, when two light beams interfere, darkness is produced at the same places. It is not possible that two corpuscles destroy each other.

2. According to this theory, the velocity of light is greater in the denser medium as compared to the rare medium. But Focault's had proved experimentally that the velocity of light is less in denser mediums as compared to the velocity of light in rare mediums.

3. According to this theory, greater the temperature of the source greater the velocity of the corpuscles. Actually, the velocity of light does not depend on the temperature of the source.

4. According to this theory, the mass of the source should decrease as it continuously emits corpuscles but it does not happen in reality.

5. In this theory two opposite assumptions are considered to explain reflection and refraction. To explain reflection and refraction through denser to rarer, the repulsive force by the surface is assumed and to explain refraction from rare to denser, the force of attraction by the surface is assumed. These assumptions are opposite and they don't have any scientific base.

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Nuclear force and its properties

Nuclear Force

A forces that act between the nucleons (i.e proton and neutron) inside the nucleus. This force is called the nuclear force.

These forces are responsible to keep the nucleons bound inside the nucleus.

Properties of Nuclear Force

There are the following properties of nuclear force is given below.

(i) These are strong nuclear forces otherwise protons cannot exist in the nucleus.

(ii) The intensity of these forces is very large. The intensity of nuclear force is maximum among, so far known forces.

(iii) It is not electrical in nature. If we assume them electrical forces, then the protons cannot reside in nucleus.

(iv) These forces do not depend on charge. The force acting between the nucleons (such as proton-proton, neutron-neutron and proton-neutron) is of same nature.

(v) These are not gravitational forces because the mass of the particles inside the nucleus is very small, while the magnitude of nuclear force is very large.

(vi) These forces are short range forces. They are confined inside the nucleus (i. e., $10^{-15} m$ equal to the diameter of nucleus). There is no existence of these forces outside the nucleus.

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Limitations of Bohr's Model

Although Bohr's model of hydrogen atom and hyarogen like atom was successful in explaining the stability and spectrum even then it has few limitations. which are as follows:

(1) This model could not explain the spectrum of atom having more than one electron.

(2) This model could not explain the relative intensity of spectral lines. (i. e., few transitions are more acceptable than others why?)

(3) When a spectral line is observed by spectroscope of high resolution power, more than one lines are observed. This is known as fine structure of spectral line. Bohr model could not explain this.

(4) Splitting of spectral lines in external magnetic field (Zeeman's effect) and in external electric field (Stark's effect) could not be explained by this model.

(5) This model could not explain the distribution of electrons in different orbit.

Few limitations of Bohr's model are removed in Somer-field's model of atom. (In this model, the orbit of electron was considered as elliptical instead of circular ). But this model also has its limitations. Vector atomic model, which is based on quantum mechanics, explains clearly the structure of atom.

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Comparison of Isothermal and Adiabatic Processes for an Ideal Gas

Isothermal Process:

1.) In this process temperature remains constant i.e.$(\Delta T= 0)$.

2.) In this process internal energy remains constant i.e. $(\Delta U= 0)$.

3.) This process takes place very slowly.

4.) In this process the system is surrounded by a perfectly conducting material, whose conductivity is infinite.

5.) This process obeys Boyle's law i.e. $(PV= constant)$.

6.) In this process the slope of isothermal curve $=-\frac{P}{V}$

7.) In this process specific heat of gas should be infinite.

Adiabatic Process:

1.) In this process exchange of heat does not take place i.e. $(\Delta Q= 0)$ but temperature changes.

2.) In this process internal energy changes.

3.) This process takes place very rapidly.

4.) In this process the system is surrounded by a perfectly insulating material, whose conductivity is zero.

5.) This process obeys Poisson's law i.e. $(PV^{\gamma} = constant)$.

6.) In this process the slope of adiabatic curve $=- \gamma \frac{P}{V}$

7.) In this process specific heat of gas should be zero.

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Concept of Perfect Gas

Concept of Perfect (ideal) Gas:

An imaginary gas whose properties are similar to the properties of a real gas (a gas whose molecules occupy space and interact with each other) at infinitely low pressure. This imaginary gas is called 'perfect gas' or ideal gas'.

According to the definition, the following properties are imagined in a perfect gas :

(1) It strictly obeys Boyle's law, Charles' law, and the law of pressure under all conditions of temperature and pressure.

(2) Its pressure coefficient and volume coefficient are exactly equal to each other.

(2) Its molecules are infinitesimally small.

(3) There is no force of attraction between its molecules. Obviously, a perfect gas cannot be converted into a liquid or solid state, because a force of attraction is necessary between the molecules in the liquid or the solid state.

In practice, the gases that are difficult to liquefy, such as oxygen, nitrogen, hydrogen, and helium can be considered as perfect, although these are also not ideally perfect.

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Failure of Wave Theory in Explaining Photoelectric Emission Effect

Description of failure of wave theory in explaining photoelectric effect:

Although reflection, refraction, interference, diffraction and polarisation etc. are explained on the basis of wave theory but the laws of photoelectric effect cannot be explained on the basis of the wave theory of light. There are three main reasons for failure:

1.) According to wave theory, as the intensity of incident light increases, incident energy also increases. Therefore, greater is the intensity, greater will be the energy absorbed by the electrons of metal and therefore greater should be the kinetic energy of photoelectrons. From experimental observations, it is clear that the maximum kinetic energy of photoelectrons does not depend on the intensity of incident light.

2.) According to wave theory, photoelectric emission should occur for all the frequencies provided that it has enough energy to emit the electrons from the metal. Although from experimental observation it is clear that if the frequency of incident light is less than the threshold frequency, photoelectrons are not emitted.

3.) The energy carried by the light waves is absorbed by all the electrons and not by a single electron. Therefore, if the intensity of light is less, for the emission of electrons, there should be some time to collect sufficient energy. Although it is clear from experimental observation, the electrons are emitted instantaneously, whatever small be the intensity of light.

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Einstein Photoelectric Emission Effect Law

Description of the Light:

According to the Albert Einstein

The light is consist of small packets or bundles of energy. These packets are called photon. The energy of each photon is $h \nu$.

Theory of Photoelectric Effect:

When the photon of ultraviolet ray is incident on the metal then this energy is used in two parts:

1.) To emit the electron from a metal surface i.e. Work Function. The electron emitted from a metal surface is called the photoelectron.

2.) Remaining energy increases the kinetic energy of the emitted photoelectron. This is the maximum kinetic energy of the photoelectron.

Let us consider

The energy of incident Ultraviolet Photon $E=h\nu$

The work function $W= h \nu_{\circ}$

The maximum kinetic energy of photo electron $K_{max}= \frac{1}{2}mv^{2}_{max}$

According to Einstein's photoelectric effect theory

$E=W+K_{max}$

$h \nu = h \nu_{\circ} + \frac{1}{2}m v^{2}_{max}$

$h \nu - h \nu_{\circ} = \frac{1}{2}m v^{2}_{max}$

$h \left( \nu - \nu_{\circ} \right) = \frac{1}{2}m v^{2}_{max}$

Where
$\nu \rightarrow$ Frequency of incident Ultraviolet ray photon
$\nu_{\circ} \rightarrow$ Threshold frequency to emit the photoelectron from the metal surface
$ v_{max} \rightarrow$ Maximum velocity of emitted photoelectron from the metal surface

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Laws of photoelectric emission

There are the following laws of photoelectric emission:

1.) The rate of emission of photoelectrons from the metal surface is directly proportional to the intensity of the incident light on the metal surface.

2.) The maximum kinetic energy of photoelectrons does not depend on the intensity of incident light.

3.) If the frequency of incident light is less than the threshold frequency then no photoelectrons will come out of the surface.

4.) If the frequency of incident light is equal to the threshold frequency then electrons will come out of the surface but the kinetic energy of emitted photoelectrons will be zero.

5.) As the frequency of incident light increases greater than the threshold frequency, the maximum kinetic energy $K_{max}$ of photoelectrons emitted from the metal surface also increases.

6.) The value of threshold frequency depends upon the nature of the metal surface and its value is different for different metals.

7.) There is no time lag in the emission of photoelectrons to the metal surface i.e., as the light of proper from frequency is made to the incident on the metal surface, photoelectrons immediately come out of the surface within no time.

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Expression for fringe width in Young's double slit experiment

Expression for fringe's width:

Let us consider two wave from slit $S_{1}$ and $S_{2}$ superimpose on each other and form interfernece patteren on the screen. The distance between the two slits is $d$ and distance between slit to screen is $D$. Now take a $n^{th}$ fringe from the centre $O$ of the screen which is at distance $y_{n}$.

So the path difference between the rays

$\Delta x = S_{2}P- S_{1}P \quad(1)$

In $\Delta S_{1}PM$

$S_{1}P^{2}=S_{1}M^{2}+PM^{2} \quad(2)$

From figure:

$S_{1}M =D$
$PM= y_{n}- \left(\frac{d}{2}\right) $

Now subtitute these values in equation $(2)$, then

$S_{1}P^{2}=D^{2}+ \left( y_{n}- \frac{d}{2} \right)^{2} \quad(3)$

In $\Delta S_{2}PN$

$S_{2}P^{2}=S_{2}N^{2}+PN^{2} \quad(4)$

From figure:

$S_{2}N =D$
$PN= y_{n} + \left(\frac{d}{2}\right) $

Now subtitute these values in equation $(4)$, then

$S_{2}P^{2}=D^{2}+ \left( y_{n} + \frac{d}{2} \right)^{2} \quad(5)$

Now subtract the equation $(3)$ in equation $(5)$

$S_{2}P^{2} - S_{1}P^{2} = \left[D^{2}+ \left( y_{n} + \frac{d}{2} \right)^{2}\right] - \left[ D^{2}+ \left( y_{n}- \frac{d}{2} \right)^{2} \right] $

$S_{2}P^{2} - S_{1}P^{2} = D^{2}+ \left( y_{n} + \frac{d}{2} \right)^{2} - D^{2} - \left( y_{n}- \frac{d}{2} \right)^{2} $

$S_{2}P^{2} - S_{1}P^{2} = \left( y_{n} + \frac{d}{2} \right)^{2} - \left( y_{n}- \frac{d}{2} \right)^{2} $

$S_{2}P^{2} - S_{1}P^{2} = y^{2}_{n} + \left(\frac{d}{2}\right)^{2} +2 y_{n} \left(\frac{d}{2}\right) - y^{2}_{n} - \left(\frac{d}{2}\right)^{2} +2 y_{n} \left(\frac{d}{2}\right) $

$S_{2}P^{2} - S_{1}P^{2} = y^{2}_{n} + \left(\frac{d}{2}\right)^{2} + y_{n} d - y^{2}_{n} - \left(\frac{d}{2}\right)^{2} + y_{n} d $

$S_{2}P^{2} - S_{1}P^{2} = y_{n} d + y_{n} d $

$ \left( S_{2}P + S_{1}P \right) \left( S_{2}P - S_{1}P \right) = 2y_{n} d$

$ \left( S_{2}P + S_{1}P \right) \Delta x = 2y_{n} d \quad \left\{from \: equation\: (1)\right\} \qquad(6)$

In this experiment, the distance between slit and screen i.e. $D$ is much greater than the distance between the slit i.e. $d$ so angle $\theta$ will be very small. So from figure

$S_{1}P = S_{2}P = D$

Substitute this value in the equation $(6)$, therefore equation $(6)$ can be written as

$ 2D \Delta x = 2y_{n} d $

$D \Delta x = y_{n}$

$\Delta x = \frac{y_{n} d}{D} \quad (7) $

This is equation of path differnce between two wave from slit $S_{1}$ and slit $S_{2}$.

Condition For Bright Fringe:

The path difference for bright fringe is

$\Delta x= n \lambda \qquad(8)$

From equation $(7)$ and equation $(8)$

$n \lambda = \frac{ d}{D} $

$y_{n} = \frac{n \lambda D}{d} \quad(9)$

This is the equation for distance of $n^{th}$ bright fringe. Now the distance of $(n+1)^{th}$ bright fringe.

$y_{n+1} = \frac{\left( n+1 \right) \lambda D}{d} \quad(10)$

The dark fringe lie between the two consecutive bright fringe. So width of the dark fringe

$\beta = y_{n+1} - y_{n}$

Now subtitute the value of $y_{n+1}$ and $y_{n}$ in the above equation $(9)$ and equation $(10)$, then

$\beta = \frac{\left( n+1 \right) \lambda D}{d} - \frac{n \lambda D}{d}$

$\beta = \frac{\lambda D}{d} \quad(11)$

This is the equation of width of dark fringe.

Condition For Dark Fringe:

The path difference for dark fringe is

$\Delta x = (2n-1) \lambda \quad(12)$

From equation $(7)$ and equation $(12)$

$ (2n-1) \lambda = \frac{y_{n} d}{D} $

$y_{n} = \frac{(2n-1) \lambda D}{d} \quad(13)$

This is the equation for distance of $n^{th}$ dark fringe. Now the distance of $(n+1)^{th}$ dark fringe.

$y_{n+1} = \frac{\left[ 2 (n+1)-1) \right] \lambda D}{d} $

$y_{n+1} = \frac{(2n+1)\lambda D}{d} \quad(14)$

The bright fringe lie between the two consecutive dark fringe. So width of the bright fringe

$\beta = y_{n+1} - y_{n}$

Now subtitute the value of $y_{n+1}$ and $y_{n}$ in the above equation $(13)$ and equation $(14)$, then

$\beta = \frac{(2n+1)\lambda D}{d} - \frac{(2n-1) \lambda D}{d}$

$\beta = \frac{\lambda D}{d} \quad(15)$

This is the equation of width of bright fringe.

The equation $(11)$ and equation $(15)$ shows that the width of bright fring and dark fringe is same.

Alternative method to find the path differnce of two wave in Young's double-slit Experiment

Let us consider: Two wave from slit $S_{1}$ and $S_{2}$ superimpose on each other and form interfernece patteren on the screen.

The distance between the two slits is $\rightarrow d$

The distance between slit to screen is $\rightarrow D$

The distance of $n^{th}$ fringe from the centre $O$ of the screen is $\rightarrow y_{n}$.

So the path difference between the two rays is

$\Delta x = S_{2}M \quad(1)$

Now from figure, In $\Delta S_{1}S_{2}M$

$sin \theta = \frac{S_{2}M}{S_{1}S_{2}} \quad(2)$

In $\Delta PNO$

$tan \theta = \frac{PO}{NO} \quad(3)$

The distance between slit and screen i.e. $D$ is much greater than the distance between the slit i.e. $d$ so angle $\theta$ will be very small i.e. $sin \theta \approx tan \theta \approx \theta $. Now equate the equation $(2)$ and equation $(3)$

$\frac{PO}{NO} = \frac{S_{2}M}{S_{1}S_{2}} \quad(4)$

Now the value from the above figure

$\frac{y_{n}}{D} = \frac{\Delta x}{d} $

$\Delta x = \frac{y_{n} d}{D} $

This is the equation of the path difference between two wave from slit $S_{1}$ and $S_{2}$.

Now the derivation for the condition for Bright and Dark fringe can be used here as it is given above.

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Analytical expression of intensity for constructive and destructive interference due to Young's double slit

Analytical expression of intensity for interference due to Young's double slit:

Let us consider two waves from slit $S_{1}$ and $S_{2}$ having amplitude $a_{1}$ and $a_{2}$ respectively superimpose on each other at point $P$ . If the displacement of waves is $y_{1}$ and $y_{2}$ and the phase difference is $\phi$ then

$y_{1}=a_{1} \: sin \omega t \qquad(1)$

$y_{2}=a_{2} \: sin \left( \omega t + \phi \right) \qquad(2)$

According to the principle of superposition:

$y=y_{1}+y_{2} \qquad(3)$

Now substitute the value of $y_{1}$ and $y_{2}$ in the above equation $(3)$

$y=a_{1} \: sin \omega t + a_{2} \: sin \left( \omega t + \phi \right)$

$y=a_{1} \: sin \omega t + a_{2} \left( sin \omega t \: cos \phi + cos \omega t \: sin \phi \right) $

$y=a_{1} \: sin \omega t + a_{2} \: sin \omega t \: cos \phi + a_{2}\: cos \omega t \: sin \phi $

$y= \left( a_{1} + a_{2} \: cos \phi \right) \: sin \omega t + a_{2} \: sin \phi \: cos \omega t \qquad(4)$

Let

$a_{1} + a_{2} \: cos \phi = A\: cos\theta \qquad(5)$

$a_{2} \: sin \phi = A\: sin\theta \qquad(6)$

Now the above equation $(4)$ can be written as

$y= A\: cos\theta \: sin \omega t + A\: sin\theta \: cos \omega t $

$y= A \left( cos\theta \: sin \omega t + sin\theta \: cos \omega t \right)$

$y= A \: sin \left( \omega t + \theta \right) \qquad(7)$

This is the equation of the resultant displacement of the waves from slit $S_{1}$ and $S_{2}$ at point $P$ on the screen.

Now square the equation $(5)$ and equation $(6)$ and then add to them so

$ A^{2} \: sin^{2}\theta + A^{2}\: cos^{2}\theta = \left( a_{1} + a_{2} \: cos \phi \right)^{2} + a^{2}_{2} \: sin^{2} \phi $

$ A^{2} \left( sin^{2}\theta + cos^{2}\theta \right) = a^{2}_{1} + a^{2}_{2} \: cos^{2} \phi + 2a_{1} \: a_{2} \: cos\phi + a^{2}_{2} \: sin^{2} \phi $

$ A^{2} = a^{2}_{1} + a^{2}_{2} \left( cos^{2}\phi + sin^{2}\phi \right) + 2a_{1} \: a_{2} \: cos\phi $

$ A^{2} = a^{2}_{1} + a^{2}_{2} + 2a_{1} \: a_{2} \: cos\phi \qquad(8)$

$ A = \sqrt{ a^{2}_{1} + a^{2}_{2} + 2a_{1} \: a_{2} \: cos\phi }\qquad(9)$

Resultant Intensity:

The resultant intensity at point $P$ due waves from slit $S_{1}$ and $S_{2}$ can be find by flollowing formula:

$I=A^{2}$

Now subtitute the va;ue of $A^{2}$ from equation $(8)$ in the above equation

$I= a^{2}_{1} + a^{2}_{2} + 2a_{1} \: a_{2} \: cos\phi \qquad(10)$

$I= I_{1} + I_{2} + 2\sqrt{I_{1} \: I_{2}} \: cos\phi \qquad(11)$

Constructive Interference:

For constructive interference the $cos\phi$ should be equal to +1 i.e. $cos\phi =1$

Phase Difference in Constructive Interference:

We know that for constructive interference $cos\phi =1$

$cos\phi = cos( 2n\pi)$

$\phi = 2n\pi \qquad(12)$

Path difference in Constructive Interference:

We know that the path difference

$\Delta x = \frac{\lambda}{2 \pi} \phi$

Now subtitute the value of $\phi $ from equation $(12)$ in the above equation

$\Delta x = \frac{\lambda}{2 \pi} 2n\pi$

$\Delta x = n \lambda \qquad(13)$

Resultant Amplitude due to Constructive Interference:

For constructive interference, the resultant amplitude is maximum at point $P$. So from equation $(9)$

$ A_{max} = \sqrt{ a^{2}_{1} + a^{2}_{2} + 2a_{1} \: a_{2} } \qquad \left( \because cos\phi =+1 \right)$

$ A_{max} = \sqrt{ \left (a_{1} + a_{2} \right)^{2}} $

$ A_{max} = \left( a_{1} + a_{2} \right) \qquad(14)$

For constructive interference, the resultant amplitude of the waves is the sum of the amplitude of individual waves.

Resultant Intensity due to Constructive Interference:

For constructive interference, the resultant intensity is maximum at point $P$. So from equation $(10)$

$I_{max}= a^{2}_{1} + a^{2}_{2} + 2a_{1} \: a_{2} \qquad \left( \because cos\phi =+1 \right)$

$I_{max}=\left( a_{1} + a_{2} \right)^{2} \qquad(15)$

From equation $(11)$

$I_{max}= I_{1} + I_{2} + 2\sqrt{I_{1} \: I_{2}} \qquad(16)$

Destructive Interference:

For destructive interference the $cos\phi$ should be equal to -1 i.e. $cos\phi = -1$

Phase Difference in Destructive Interference:

We know that for destructive interference $cos\phi = -1$

$cos\phi = cos \left( \left( 2n \pm 1 \right)\pi \right)$

$\phi = \left( 2n \pm 1 \right)\pi \qquad(17)$

Path difference in Destructive Interference:

We know that the path difference

$\Delta x = \frac{\lambda}{2 \pi} \phi$

Now subtitute the value of $\phi $ from equation $(17)$ in the above equation

$\Delta x = \frac{\lambda}{2 \pi} \left( 2n \pm 1 \right)\pi$

$\Delta x = \left( 2n \pm 1 \right) \frac{\lambda}{2} \qquad(18)$

Resultant Amplitude due to Destructive Interference:

For the destructive interference, the resultant amplitude is minimum at point $P$. So from equation $(9)$

$ A_{min} = \sqrt{ a^{2}_{1} + a^{2}_{2} - 2a_{1} \: a_{2} } \qquad \left( \because cos\phi =-1 \right)$

$ A_{min} = \sqrt{ \left (a_{1} - a_{2} \right)^{2}} $

$ A_{min} = \left( a_{1} - a_{2} \right)$

For constructive interference, the resultant amplitude of the waves is the difference in amplitude of individual waves.

Resultant Intensity due to Destructive Interference:

For the destructive interference, the resultant intensity is minimum at point $P$. So from equation $(10)$

$I_{min}= a^{2}_{1} + a^{2}_{2} - 2a_{1} \: a_{2} \qquad \left( \because cos\phi =-1 \right)$

$I_{min}=\left( a_{1} - a_{2} \right)^{2}$

From equation $(11)$

$I_{min}= I_{1} + I_{2} - 2\sqrt{I_{1} \: I_{2}} $

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Viscosity, Viscous force and Coefficient of Viscosity

Definition of Viscosity:

It is the property of a fluid that opposes the relative motion between its adjacent layers. This property of the fluid is known as viscosity. It is also called the resistance of fluid to flow or deformation or fluid thickness.

Effect of temperature on Viscosity:

The viscosity of the fluid decreases sharply with the temperature rise and becomes zero at boiling temperature. On the other hand, the viscosity of the gases increases with the temperature rise.

Definition of Viscous Force (Internal Frictional Force):

When a layer of fluid slide over another layer of the same fluid then an internal tangential frictional force act between them which opposes the relative motion between the layers. This tangential force is called viscous force or internal frictional force.

In the absence of external force, the viscous force would soon bring the fluid to rest.

Factor affecting the viscous force:

There are the following factors that affect the viscous force-

1.) The viscous force is directly proportional to the contact area of the layers. i.e.

$F \propto A \qquad(1)$

Where $A \rightarrow$ The contact area of the layers

2.) The viscous force is directly proportional to the velocity gradient between the layers. i.e.

$F \propto \frac{\Delta v_{x}}{\Delta z} \qquad(2)$

Where $\frac{\Delta v_{x}}{\Delta z} \rightarrow$ The velocity gradient that is shown in the figure below

From equation $(1)$ and equation $(2)$

$F \propto A \: \frac{\Delta v_{x}}{\Delta z}$

$F = \pm \: \eta \: A \: \frac{\Delta v_{x}}{\Delta z} \qquad(3)$

Where

$\eta \rightarrow$ It is a constant and also known as the "coefficient of viscosity" of the fluid.

$ \pm \rightarrow$ It indicates that the viscous force $F$ between two layers of fluid is a mutually interacting force. As shown above in figure (B), A layer that is just above layer $A$ exerts a force in the forward direction while a layer that is just below layer $A$ exerts an equal and opposite force i.e. in the backward direction.

Definition of Coefficient of Viscosity:

If $A=1$ and $\frac{\Delta v_{x}}{\Delta z} = 1$, then from equation $(3)$

$\eta = 1$

So from the above equation,  If the contact area and velocity gradient are units then the viscous force between the fluid is known as the coefficient of velocity.

Dimension of coefficient of viscosity:

$\left[ M L^{-1} T^{-1} \right]$

Unit of coefficient of viscosity:

$Kg-m^{-1}s^{-1}$

Here

$1 \: Kg-m^{-1}s^{-1} = 10\: poise = 1 \: decapoise$

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Brief Description of Liquid Lasers

Brief Description: (Liquid Lasers)

Due to their homogeneous properties and a very high optical cavity of liquids, these are also used as active materials in lasers. Liquid lasers are four-level lasers that use liquids as active material or lasing medium. In these lasers, laser tubes are filled with liquid instead of laser rods as in solid-state lasers or gas in gas lasers. Liquid laser medium has some advantages like very high gain, no cracking for high output power, feasibility of cooling the liquid by circulation, narrow frequency spectrum, etc. In liquid lasers, optical pumping is required for laser action. Optical pumping includes flash tubes, nitrogen lasers, excimer lasers, etc. A rare earth ion dissolved in a solution makes it possible to obtain optically pumped laser action in liquids. The first successful liquid laser was reported by using europium ions ($Eu^{+3}$) in which a sharp and strong laser transition was observed at $6131 A^{\circ}$ wavelength. In this laser, a europium chelate ($EuB_{4}P$) was prepared with benzovlacetate and dissolved in alcohol to give a europium concentration $1.2 \times 10^{19} centers/cm^{3}$. Due to the high absorption coefficient of chelate, it gives rise to pumping problems and their viscosity is so high that circulating motion is not feasible. The best solution to date is the liquid selenium oxychloride ($SeOCl_{2}$) which has a low refractive index, good optical transmission, and a density comparable to glass but it is highly toxic.

To reduce the problem in laser action due to high viscosity and pumping in chelate, the organic dyes are used as the lasing medium in liquid lasers. Dyes are organic substances that absorb in the near ultraviolet, visible, or near-infrared region of the spectrum. When organic dyes are used as a lasing medium. usually, as a liquid solution, in a laser, it is called a dye laser. Examples of some dyes are rhodamine, coumarin, fluorescein, etc. A variety of solvents can be used in dye lasers. Some of the solvents used are water, glycol, ethanol, methanol, hexane, cyclohexane, etc. The lasers using dyes like coumarin, xanthene, quinoline, etc. emit laser radiations in the range of wavelengths $400-500 \: nm, 500-70O \: nm, 400-4300 \: nm$, etc, respectively. These lasers have broad spectral bandwidth and fluorescent spectrum and emission in any region of the visible spectrum can be chosen from a large number of dyes. These lasers produce ultra-short pulses of half-width than with any other lasers. These lasers are the cheapest and one of the most widely tunable lasers in the visible region. Dye lasers Can be used as solid, liquid, and gas lasers but liquid solutions of dyes are convenient as their concentration can be controlled

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