Showing posts with label Kinematics Theory Of Gases. Show all posts
Showing posts with label Kinematics Theory Of Gases. Show all posts

Concept of Perfect Gas

Concept of Perfect (ideal) Gas:
An imaginary gas whose properties are similar to the properties of a real gas (a gas whose molecules occupy space and interact with each other) at infinitely low pressure. This imaginary gas is called 'perfect gas' or ideal gas'.
According to the definition, the following properties are imagined in a perfect gas :

(1) It strictly obeys Boyle's law, Charles' law, and the law of pressure under all conditions of temperature and pressure.

(2) Its pressure coefficient and volume coefficient are exactly equal to each other.

(2) Its molecules are infinitesimally small.

(3) There is no force of attraction between its molecules. Obviously, a perfect gas cannot be converted into a liquid or solid state, because a force of attraction is necessary between the molecules in the liquid or the solid state.

In practice, the gases that are difficult to liquefy, such as oxygen, nitrogen, hydrogen, and helium can be considered as perfect, although these are also not ideally perfect.

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  • Classical world and Quantum world

  • Inadequacy of classical mechanics

  • Drawbacks of Old Quantum Theory

  • Bohr's Quantization Condition

  • Energy distribution spectrum of black body radiation

  • Energy distribution laws of black body radiation

  • The Compton Effect | Experiment Setup | Theory | Theoretical Expression | Limitation | Recoil Electron

  • Davisson and Germer's Experiment and Verification of the de-Broglie Relation

  • Significance of Compton's Effect

  • Assumptions of Planck’s Radiation Law

  • Derivation of Planck's Radiation Law

  • de-Broglie Concept of Matter wave

  • Definition and derivation of the phase velocity and group velocity of wave

  • Relation between group velocity and phase velocity ($V_{g}=V_{p}-\lambda \frac{dV_{p}}{d\lambda }$)

  • Group velocity is equal to particle velocity($V_{g}=v$)

  • Product of phase velocity and group velocity is equal to square of speed of light ($V_{p}.V_{g}=c^{2}$)

  • Heisenberg uncertainty principle

  • Generation of wave function for a free particle

  • Physical interpretation of the wave function

  • Derivation of time dependent Schrodinger wave equation

  • Derivation of time independent Schrodinger wave equation

  • Eigen Function, Eigen Values and Eigen Vectors

  • Postulate of wave mechanics or Quantum Mechanics

  • Quantum Mechanical Operators

  • Normalized and Orthogonal wave function

  • Particle in one dimensional box (Infinite Potential Well)

  • Minimum Energy Or Zero Point Energy of a Particle in an one dimensional potential box or Infinite Well

  • Normalization of the wave function of a particle in one dimension box or infinite potential well

  • Orthogonality of the wave functions of a particle in one dimension box or infinite potential well

  • Eigen value of the momentum of a particle in one dimension box or infinite potential well

  • Schrodinger's equation for the complex conjugate waves function

  • Probability Current Density for a free particle in Quantum Mechanics

  • Ehrenfest's Theorem and Derivation

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