Drawbacks of Old Quantum Theory

Planck's quantum hypothesis with its application and extension to explain the black body radiation like the photo-electric effect, the Compton effect, the variation of specific heat of solid with temperature and the spectrum of hydrogen is now called the Old quantum theory. Through these phenomena are successfully explained by the theory, there are numerous drawbacks of the theory. A few of them are as follows.

1.) Bohr's quantization rules are arbitrary. The theory does not provide a physical explanation for the assumptions.

2.) The old quantum theory cannot be applied to explain the spectra of helium and of more complex atoms.

3.) It can provide only a qualitative and incomplete explanation of the intensities of the spectral lines.

4.) It can not explain the dispersion of light.

5.) The theory of non-harmonic vibrations of systems cannot be applied to explain the vibrations of systems.

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  • Classical world and Quantum world

  • Inadequacy of classical mechanics

  • Drawbacks of Old Quantum Theory

  • Bohr's Quantization Condition

  • Energy distribution spectrum of black body radiation

  • Energy distribution laws of black body radiation

  • The Compton Effect | Experiment Setup | Theory | Theoretical Expression | Limitation | Recoil Electron

  • Davisson and Germer's Experiment and Verification of the de-Broglie Relation

  • Significance of Compton's Effect

  • Assumptions of Planck’s Radiation Law

  • Derivation of Planck's Radiation Law

  • de-Broglie Concept of Matter wave

  • Definition and derivation of the phase velocity and group velocity of wave

  • Relation between group velocity and phase velocity ($V_{g}=V_{p}-\lambda \frac{dV_{p}}{d\lambda }$)

  • Group velocity is equal to particle velocity($V_{g}=v$)

  • Product of phase velocity and group velocity is equal to square of speed of light ($V_{p}.V_{g}=c^{2}$)

  • Heisenberg uncertainty principle

  • Generation of wave function for a free particle

  • Physical interpretation of the wave function

  • Derivation of time dependent Schrodinger wave equation

  • Derivation of time independent Schrodinger wave equation

  • Eigen Function, Eigen Values and Eigen Vectors

  • Postulate of wave mechanics or Quantum Mechanics

  • Quantum Mechanical Operators

  • Normalized and Orthogonal wave function

  • Particle in one dimensional box (Infinite Potential Well)

  • Minimum Energy Or Zero Point Energy of a Particle in an one dimensional potential box or Infinite Well

  • Normalization of the wave function of a particle in one dimension box or infinite potential well

  • Orthogonality of the wave functions of a particle in one dimension box or infinite potential well

  • Eigen value of the momentum of a particle in one dimension box or infinite potential well

  • Schrodinger's equation for the complex conjugate waves function

  • Probability Current Density for a free particle in Quantum Mechanics

  • Ehrenfest's Theorem and Derivation

  • Momentum wave function for a free particle

  • Wave function of a particle in free state

  • One dimensional Step Potential Barrier for a Particle

























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