Newton's Corpuscular Theory
In the year 1675, Newton proposed the corpuscular theory of light to explain the existing phenomenon of light. There are the following assumptions of this theory:
1. The light consists of very small, lightweight, and invisible particles. These particles are known as corpuscles.
2. These corpuscles move with the velocity of light in a homogeneous medium in all possible directions in a straight line and they carry kinetic energy with them.
3. When these corpuscles fall on the retina of the eye, they produce the sensation of vision.
4. The size of corpuscles of different colors is different (ie, the color of light depends on the size of the corpuscle).
(A) Success of Carpuscles Theory
Based on this theory, the following facts related to light were explained successfully:
1. The light has energy: Since corpuscles have kinetic energy. Therefore, the energy of the light beam is due to the kinetic energy of the corpuscles.
2. Motion of light along a straight line: Since velocity of the corpuscle is very high, the effect of external forces on it is
negligible. Therefore, it moves in a straight line.
3. Motion of light in vacuum: Corpuscles can move through vacuum.
4. Reflection of light: To explain the reflection of light, Newton assumed that when a corpuscle reaches close to a reflecting surface, then the surface repels it with a force whose direction is perpendicular to the surface and whose magnitude decreases sharply as the distance of corpuscles increases from the surface.
In Figure, let $PO$ be a reflecting surface and $P'Q'$ be an imaginary surface just above it at negligible height. When a light corpuscle moves towards the surface, then it moves along a straight line from $A$ to $B$ (since the force is zero). As it reaches the point $B$ of surface $PQ$, a repulsive force starts acting perpendicular to the surface (upward in the figure). Let $i$ is an angle of incidence at point $B$, then the velocity of the corpuscles at point $B$ has two components- component parallel to surface $V_{||} =v \: sin \: i$ and component perpendicular to surface $V_{|} = v \: cos \: i$. After crossing point $B$, the parallel component remains same but the perpendicular component decreases. At point $C$ of surface $PQ$, the perpendicular component becomes zero. After this direction of the perpendicular component changes and the corpuscles move along path CD. Beyond D again it moves along a straight line as the force becomes ineffective. If $r$ is the angle of reflection at point $D$, then the parallel component of velocity at $D$ will be $v\: sin\: r$. Since the parallel component remains constant. Therefore, comparing them at points $B$ and $D$.
$v \: sin \: i=v \: sin\: r$
$sin \: i= sin\: r$
$i=r$
i.e., the above equation shows that the incident angle and the reflected angle are equal. In the figure above, incident ray, reflected ray and normal all three are in the plane of paper. Therefore laws of reflection are verified.
5. Refraction of light: To explain the refraction of light, Newton considered two different situations :
a.) When the light goes from a denser medium to a rare medium: In this condition when the corpuscle reaches near the surface, the surface exerts a normal repulsive force on it. As a result, the perpendicular component of velocity of the corpuscles decreases however it does not reduce to zero as in the case of refraction. Therefore, enters the second medium with a reduced perpendicular component and same constant value of the parallel component i.e., moves along a straight line bending away from normal.
If $i$ and $r$ are the angle of incidence and angle of refraction and $v_{1}$ and $v_{2}$ are the velocity of corpuscle in medium first and second medium. If the parallel component is constant,
$v_{1} \: sin \: i =v_{2} \: sin\: r$
$\frac{sin \: i}{sinr} =\frac{v_{2}}{v_{1}}$
From Figure
$i \lt r$
Therefore
$sin \: i \lt sin\: r$
$v_{2} \lt v_{1}$
Therefore, from the corpuscular theory, velocity light in a denser medium ($v_{1}$) is greater than the velocity light in a rare medium ($v_{2}$).
b.) When the light goes from a rare medium to a denser medium: In this condition when the corpuscle reaches near to the surface, the surface attracts it normally. As a result, the normal component of its velocity increases. Therefore, the corpuscular enters the second medium with an increased normal component and the same parallel component of velocity and moves along a straight line bending towards the normal.
$v_{1} \: sin \: i =v_{2} \: sin\: r$
$\frac{sin \: i}{sinr} =\frac{v_{2}}{v_{1}}$
From Figure
$i \gt r$
Therefore
$ sin \: i \gt sin\: r$
$v_{2} \gt v_{1}$
Therefore, velocity light in a denser medium ($v_{1}$) is greater than the velocity light in a rare medium ($v_{2}$).
B) Failure of the Corpuscles Theory
The following are the main reasons for the failure of this theory:
1. Interference, diffraction, polarisation of light, and the photoelectric effect, etc. can not be explained using this principle. For example, in interference, when two light beams interfere, darkness is produced at the same places. It is not possible that two corpuscles destroy each other.
2. According to this theory, the velocity of light is greater in the denser medium as compared to the rare medium. But Focault's had proved experimentally that the velocity of light is less in denser mediums as compared to the velocity of light in rare mediums.
3. According to this theory, greater the temperature of the source greater the velocity of the corpuscles. Actually, the velocity of light does not depend on the temperature of the source.
4. According to this theory, the mass of the source should decrease as it continuously emits corpuscles but it does not happen in reality.
5. In this theory two opposite assumptions are considered to explain reflection and refraction. To explain reflection and refraction through denser to rarer, the repulsive force by the surface is assumed and to explain refraction from rare to denser, the force of attraction by the surface is assumed. These assumptions are opposite and they don't have any scientific base.
Nuclear force and its properties
Nuclear Force
Properties of Nuclear Force
There are the following properties of nuclear force is given below.
(i) These are strong nuclear forces otherwise protons cannot exist in the nucleus.
(ii) The intensity of these forces is very large. The intensity of nuclear force is maximum among, so far known forces.
(iii) It is not electrical in nature. If we assume them electrical forces, then the protons cannot reside in nucleus.
(iv) These forces do not depend on charge. The force acting between the nucleons (such as proton-proton, neutron-neutron and proton-neutron) is of same nature.
(v) These are not gravitational forces because the mass of the particles inside the nucleus is very small, while the magnitude of nuclear force is very large.
(vi) These forces are short range forces. They are confined inside the nucleus (i. e., $10^{-15} m$ equal to the diameter of nucleus). There is no existence of these forces outside the nucleus.
A forces that act between the nucleons (i.e proton and neutron) inside the nucleus. This force is called the nuclear force.These forces are responsible to keep the nucleons bound inside the nucleus.
Limitations of Bohr's Model
Although Bohr's model of hydrogen atom and hyarogen like atom was successful in explaining the stability and spectrum even then it has few limitations. which are as
follows:
(1) This model could not explain the spectrum of atom having more than one electron.
(2) This model could not explain the relative intensity of spectral lines. (i. e., few transitions are more acceptable than others why?)
(3) When a spectral line is observed by spectroscope of high resolution power, more than one lines are observed. This is known as fine structure of spectral line. Bohr model could not explain this.
(4) Splitting of spectral lines in external magnetic field (Zeeman's effect) and in external electric field (Stark's effect) could not be explained by this model.
(5) This model could not explain the distribution of electrons in different orbit.
Few limitations of Bohr's model are removed in Somer-field's model of atom. (In this model, the orbit of electron was considered as elliptical instead of circular ). But this model
also has its limitations. Vector atomic model, which is based on quantum mechanics, explains clearly the structure of atom.
Comparison of Isothermal and Adiabatic Processes for an Ideal Gas
Isothermal Process:
1.) In this process temperature remains constant i.e.$(\Delta T= 0)$.
2.) In this process internal energy remains constant i.e. $(\Delta U= 0)$.
3.) This process takes place very slowly.
4.) In this process the system is surrounded by a perfectly conducting material, whose conductivity is infinite.
5.) This process obeys Boyle's law i.e. $(PV= constant)$.
6.) In this process the slope of isothermal curve $=-\frac{P}{V}$
7.) In this process specific heat of gas should be infinite.
Adiabatic Process:
1.) In this process exchange of heat does not take place i.e. $(\Delta Q= 0)$ but temperature changes.
2.) In this process internal energy changes.
3.) This process takes place very rapidly.
4.) In this process the system is surrounded by a perfectly insulating material, whose conductivity is zero.
5.) This process obeys Poisson's law i.e. $(PV^{\gamma} = constant)$.
6.) In this process the slope of adiabatic curve $=- \gamma \frac{P}{V}$
7.) In this process specific heat of gas should be zero.
Concept of Perfect Gas
Concept of Perfect (ideal) Gas:
(1) It strictly obeys Boyle's law, Charles' law, and the law of pressure under all conditions of
temperature and pressure.
(2) Its pressure coefficient and volume coefficient are exactly equal to each other.
(2) Its molecules are infinitesimally small.
(3) There is no force of attraction between its molecules. Obviously, a perfect gas cannot be converted
into a liquid or solid state, because a force of attraction is necessary between the molecules in the
liquid or the solid state.
In practice, the gases that are difficult to liquefy, such as oxygen, nitrogen, hydrogen, and helium
can be considered as perfect, although these are also not ideally perfect.
An imaginary gas whose properties are similar to the properties of a real gas (a gas whose molecules occupy space and interact with each other) at infinitely low pressure. This imaginary gas is called 'perfect gas' or ideal gas'.According to the definition, the following properties are imagined in a perfect gas :
Failure of Wave Theory in Explaining Photoelectric Emission Effect
Description of failure of wave theory in explaining photoelectric effect:
Although reflection, refraction, interference, diffraction and polarisation etc. are explained on the basis of wave theory but the laws of photoelectric effect cannot be explained on the basis of the wave theory of light. There are three main reasons for failure:
1.) According to wave theory, as the intensity of incident light increases, incident energy also increases. Therefore, greater is the intensity, greater will be the energy absorbed by the electrons of metal and therefore greater should be the kinetic energy of photoelectrons. From experimental observations, it is clear that the maximum kinetic energy of photoelectrons does not depend on the
intensity of incident light.
2.) According to wave theory, photoelectric emission should occur for all the frequencies provided that it has enough energy to emit the electrons from the metal. Although from experimental observation it is clear that if the frequency of incident light is less than the threshold
frequency, photoelectrons are not emitted.
3.) The energy carried by the light waves is absorbed by all the electrons and not by a single electron. Therefore, if the intensity of light is less, for the emission of electrons, there should be some time to collect sufficient energy. Although it is clear from experimental observation, the
electrons are emitted instantaneously, whatever small be
the intensity of light.
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